Carbonylation相关论文
Cu/Pd-catalyzed borocarbonylative trifunctionalization of alkynes and allenes:synthesis of β-geminal
Functionalized bisboryl compounds have recently emerged as a new class of synthetically useful building blocks in organi......
Importance of metal location in M-H zeolite for synergistically catalyzing dimethyl ether carbonylat
Mordenite (MOR) has shown great potential to catalyze dimethyl ether (DME) carbonylation to methyl acetate (MA) in indus......
Theoretical study of palladium-catalyzed sp3 N-H bond activation oxidative carbonylation of hydrazid
A systematic theoretical study has been carried out for the palladium-catalyzed intramolecular cyclocarbonylation reacti......
Synthesis of diversely substituted 2-(furan-3-yl)acetates from allenols through cascade carbonylatio
Furan derivatives have attracted tremendous attention due to their wide presence in numerous natural products,pharmaceut......
Imidazopyridine compounds are important nitrogen-containing heterocycles existing widely in natural products,pharmaceuti......
An unprecedented palladium-catalyzed asymmetric carbamoyl-carbonylation of tethered alkenes with CO and alcohols has bee......
Three-component coupling reactions of arylborons,carbon monoxide,and aryl halides,have been developed as powerful to......
Integrating the reverse water gas shift reaction(H2+CO2→CO+H2O)with catalytic carbonylation is an effective pathway......
A Palladium-catalyzed Oxidative Carbonylative Esterification of 3-Phenylquinolin-4(1H)-one for the S
Carbonylation of organic compounds with CO as carbon-atom source have been and continued to be an attractive synthet......
The modern research is based on the proper design, evaluation, and understanding of the catalysts for organic reactions ......
...
In the reaction cycle for methanol carbonylation catalyzed by Rh complex, the structure geometries of the reactant, inte......
The inner structure of Rh/Ys,a novel high efficiency supported catalyst,and the spreading of Rh on the Ys surface were a......
Radical Carbonylation under Low CO Pressure:Synthesis of Esters from Activated Alkylamines at Transi
High CO pressure (＞ 40 bar) is usually needed in radical carbonylation reactions in the absence of metal catalyst.In this......
Although tandem reactions offer rapid access to structurally complex molecules in one-pot reaction,the selectivity issue......
利用大位阻芳基异腈作为羰基源,发展了钯催化下的烯丙基羰基化Negishi偶联反应.大位阻芳基异腈的使用可以有效地避免羰基化反应过......
近年来,由于其接近100%的原子利用率和独特的催化性能,单原子催化剂研究受到了极大的关注。近年来,人们针对二氧化碳选择性催化转......
A density functional theory study on the mechanism of dimethyl ether carbonylation over heteropolyac
Dimethyl ether (DME) carbonylation is considered as a key step for a promising route to produce ethanol from syngas.Hete......
It is a multi-phase-catalyzed reaction to produce calcium phenylpyruvate by double carbonylation of benzylchloride. Base......
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生......
A Novel Sulfided Mo/C Catalyst for Direct Vapor Phase Carbonylation of Methanol at Atmospheric Press
The direct carbonylation of methanol, without any halide in the feed as a promoter, ispresented. A series of Mo catalyst......
Study on the Synthesis of Phenylacetic Acid by Carbonylation of Benzyl Chloride under Normal Pressur
The influences of some factors on the yield of phenylacetic acid in the carbonylation of benzyl chloride were studied in......
Ab initio study on the mechanism of rhodium-complexcatalyzed carbonylation of methanol to acetic aci
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
The basic problem of a homogeneous catalytic process is the separation of products from catalytic reaction system. Two m......
Methanol carbonylation is the main process for producing acetic acid. The current technology is based on precious rhodiu......
氢氧化钙羰基化合成甲酸钙的实验结果表明其主要产物为甲酸钙，此外还有少量的碳酸钙副产物。据此，对氢氧化钙羰基化合成甲酸钙的反应......
通过实验研究优化了用于醋酸甲酯羰基化制醋酐的乙酰吗啉-铑配合物新催化体系。结果表明，铑溶液质量浓度为400μg/L ，锂盐质量浓度为......
Photopromoted carbonylation of olefins with carbon dioxide and labelling studies with 13CO2 and 13CH
Photopromoted carbonylation of olefins with carbon dioxide can be completed in ambient conditions (room temperatures and......
A green synthesis route of diethyl malonate by palladium catalyzed carbonylation of ethyl chloroacetate in the presence ......
The Zn-Cu(Ⅰ)/HMCM-41 catalysts were successfully prepared in laboratory scale by solid-state ion exchange with CuCl sal......
A Novel Sulfided Mo/C Catalyst for Direct Vapor Phase Carbonylation of Methanol at Atmospheric Press
The direct carbonylation of methanol, without any halide in the feed as a promoter, ispresented. A series of Mo catalyst......
Kinetics of synthesis of methyl formate from carbon monoxide and methanol, using sodium methoxide as the catalyst and py......
The basic problem of a homogeneous catalytic process is the separation of products from catalytic reaction system. Two m......
Benzoxazolinones are a known class of commercially available compounds that are widely used in agriculture and industry.......
N-pentamethylene-N′-aryl ureas are important fine chemical intermediates in industries of dye, pigment, pharmaceutical ......
A novel heterogeneous Ni-Zn/C catalyst was used for vapor-phase carbonylation of ethanol under atmospheric pressure. Exp......
The carbonylation of phenyl bromide catalyzed by Co(OAc)2 has been investigated with PhCOPh as a sensitizer under visibl......
甲苯羰基化法合成对甲基苯甲醛进而氧化合成对苯二甲酸的生产工艺，原子利用率高、工艺简单、生产成本低，工业化生产新工艺的开发具有......
使用gen（B3LYP／6-31G（d）：STO-3G）混合基组的量子化学计算方法，探讨了当H，F和CH3作为取代基时，LAI[η2-C2R2]（L=HC[（CMe）（NAr）]2，Ar=2，6-iPrzC6H3）与C......
采用浸渍法制备适合乙醇羰基化合成制备丙酸的负载型催化剂,对其性能进行了考察,并在此基础上开发出新型的三元复合催化剂。......
采用有效核近似从头算方法,在HF/LANL2DZ水平下用Berny优化法,对吡啶甲酸铑阳离子催化剂催化甲醇羰基化反应中各基元反应的中间体......
考察了在间二甲苯液体介质中,甲醇羰基化合成甲酸甲酯的反应动力学.结果表明,间二甲苯对反应速率有一定影响.随着溶液中间二甲苯含......
在温和条件下，将原位合成的Na[Co(CO4)]合物首次用于催化一氯丙酮羰基化合成乙酰乙酸甲酯，考察了不同的碱性试剂、一氧化碳压力及反......
对氢氧化钙羰基化合成甲酸钙的工艺进行了初步研究,考察了温度、一氧化碳分压、不同添加剂和搅拌速率对反应速率的影响,实验结果表......
用浸渍法制备了负载型Ni-Mo-La/AC复合催化剂,并在平推流反应器中对甲醇气相羰基化催化反应进行了动力学数据的测定。实验证明,醋......
用PdCl2（PPh3）2／PPh3／P-CH3C6H4SO3H复合催化体系，在间歇高压釜中，以二甲苯为溶剂，在一定的反应温度、CO／H2压力和薄荷醇与异丁烯浓度下，研......
简述了分别以一氧化碳、二氧化碳与甲醇、二甲醚等进行羰基化反应合成碳酸二甲酯（DMC）的研究进展。并分别对各种工艺路线进行了分析......
碳酸二乙酯是一种重要的有机化工原料,可广泛用于合成农药如脱叶灵,医药如喹啉酮衍生物,中间体3-氧硫代羧酸酯,还可用于电子管阴极......
